Battery Basics

fechter

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There are many types of batteries available for EV use. Each has its advantages and disadvantages. A great resource for learning more is:
http://www.batteryuniversity.com

Some of the main types are listed here:

safe said:
partone-3.gif

Table of How and When to Charge Batteries:
http://www.batteryuniversity.com/partone-23.htm
 
patrick_mahoney said:
For cobalt lithium ion. Lithium polymer cells have most of the same issues (except discharge rate) as cobalt lithium ion.

Other lithium chemistries (LiMn, Li3PO4, LiFePO4) are different.

* Permanent changes after a long time spent unused but fully charged
Cobalt lithium ion gradually loses capacity over time. This is due to an oxidixing effect inside the cell and happens whether or not you use the cell or not. The capacity loss over time is worst at high temperatures, fully charged. It is lowest at 40-50% capacity, a few degrees below freezing
* Temporary changes after a long time spent unused but initially fully charged
Cobalt lithium ion lose charge (self-discharge) very slowly when stored unused but fully charged. Self-discharge is worst at higher temperatures and ranges between 5-10% per month depending on chemistry and temperature.
* Permanent changes after any length of time spent partially charged
As mentioned above, cobalt lithium ion always loses capacity over time due to oxidation. Leaving the cell partially discharged is better than leaving it fully charged.
* Permanent changes after many recharges from a significantly-discharged state
This is the preferred usage model for cobalt lithium ion. You don't want to fully charge them because the oxidation loss is greatest at the fully charged state. Longest calendar and cycle life appears to be seen when running between a 40% DoD and 60% DoD state. But I don't have a lot of research to quote to back me up on this - although a couple of books seem to indicate that this is the case.
* Permanent changes after many recharges from a slightly-discharged state
You generally want to be less charged than merely "slightly discharged" to avoid capacity losses due to oxidation.
* Any changes (permanent or temporary) in response to non-fatal temperature highs or lows (does it suffer at 40 degrees Celsius? 0 degrees?)
Cobalt lithium ion loses capacity temperarily at very low temperatures, and loses capacity permanently at very high tempatures. Significant temporary capacity loss is seen below 40F/5Celsius.
* Does it suffer from rapid discharge?
Generally cobalt lithium ion do not like rapid discharge at all. Most manufacturers spec the cells at 1-2C max discharge, with the typical being 1.5C. Exceeding this increases heat in the cell which reduces the operational life of the cells.
* Does it suffer from rapid recharge?
Generally cobalt lithium ion do not like rapid charging at all. Most manufacturers spec the cells at 1C max charge rate. Exceeding 0.5C charge rate reduces the operational life of the cells. In fact, a really low charge rate can significantly extend the operational life of the cells.

Other things to avoid with cobalt lithium ion cells to extend the operational life of the cells that weren't mentioned above:
Don't charge at, below, or near freezing - you can permanently damage the cells.
Don't discharge the cells below 3V per cell - you can permanently damage the cells.


Data to back up what I wrote above:
http://en.wikipedia.org/wiki/Lithium_ion_battery
http://www.batteryuniversity.com/partone-5A.htm
http://www.batteryuniversity.com/partone-19.htm
 
NiCd batteries will self discharge when stored, though they prefer storage in a discharged state. I've had NiCd's that were over 15 years old, but unused that worked just like new ones. Amazing.

In normal use, their lifespan does not seem to depend on their storage state of charge. You can leave them dead for years with no ill effect.

They do not like staying on float charge for weeks on end. Cells tend to form 'dendrites' (little spikes) on the plates that will eventually grow and penetrate the insulator and cause the cell to short.

Like most batteries, the shallower the discharge, the longer the cycle life.
NiCds used on shallow cycles repeatedly may develop "memory effect", but that's way overblown as a problem. An occasional deep discharge will restore capacity.

Like most batteries, performance drops with temperature, but NiCd's do comparatively well in cold temperatures. At high temperatures, the cells perform better, but thier lifespan will be reduced.

NiCd can be discharged at extremely high rates with no damage and little loss of capacity.

On the downside, Cadmium is highly toxic and these batteries must be recycled properly.
 
Here's a good reference for lead-acid batteries:
http://homepages.which.net/~paul.hills/Batteries/Batteries.html

Thanks, Tyler
 
Here's another battery information resource.
This one is more up-to-date than some of the others.


RealPeterPan said:
Just found a pretty large knowledge database about batteries of any kind like

-Battery Types

-Battery Chemistries (Lead acid, NiMH, NiCa, LiPo, LiFePo, LiIon, etc.)

-Battery Performance

-Battery Glossary

-Battery History

-Battery Search Engine

Its from a UK battery distributor (which btw claims to made the Bosch 36V packs)

Well here you go:

http://www.axeonpower.com/index.htm


Regards Sven Brinkhoff
 
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