there are 2 capacitors on the evg controller's brain board. In some controllers I have opened they were 50v in others they were 35v. there is also a 35 volt capacitor on another board which if I remember right has the relay for the lighting system. the lights btw are limited to 24v. 36 will burn out the resistors in the LED tail light. the headlamp will work at 36v but eventually will melt the plastic reflector.
the 24v hub motors will work fine at 36v as long as you keep the amps reasonably low. I ran one for a year or so w/ a cheap 36v brushed controller which was rated at 500w. speed was increased to a bit over 20mph and hill climbing power seemed to remain about the same. the evg throttle is a potentiometer style and sends a full throttle signal of about 2.7 volts to the evg controller rather than the 5 or so volts a modern controller needs for full throttle. sending 10 to 12 volts through the evg throttle allowed me to use it w/ the new controller. the state of charge lights on the evg throttle are 6v led's which are illuminated by the logic processor in the evg control unit, not a stand alone volt meter like in modern throttles. I ran the 6v signal from the new controller's throttle output to one just so I would have a light on my bars to show that the bike was turned on. you would probably be better off just getting a 36v throttle with soc lights. I liked the way the evg thumb throttle felt and wanted to keep using it though.
as Dogman says, the thermal switch in the evg hub is important. one simple solution, if you go with a modern throttle, is to run the throttle power through the switch, if your motor overheats it will effectively kill your throttle until it cools down. I did something similar but in actuality my motor never once over heated on 36v. I didn't have a watt meter back then to check it so it is highly probable that my "500W" controller was in fact quite a bit lower amps than stated.
if you do decide to replace the heinzmann w/ a modern 48 (or maybe even 36) volt brush-less set up you will find that you won't need a second motor for the front IMO. not sure about the topography in Leadville, CO. but I get up some pretty long steep hills here in Seattle Wa just fine.
for what it is worth, I wrote a post a while back detailing how to fit 36v of lifepo4 into an evg 24v battery case here: http://visforvoltage.org/forum/10456-ev-global-24-volt-ebike-problem
and just for the record, although I wouldn't recommend using SLA, it should (maybe) be noted that 6 6v 7ah sla batteries will NOT fit into an unmodified 24v evg battery case. they will fit in a 36v evg case which is about 1/8 inch wider. 2 12v 7ah in series w/ 2 6v 7ah will just fit in a 24v case. but again, friends don't let friends drive SLA.
DC