Yes that could work. As you probably know, you want to find a high Wh/Kg (energy density). That one is reasonable (about 176).
So far I haven't found a LiPo charger that can charge a high voltage pack (with balancing capability), so unless you can find one, you'd have to charge them separately... so you'd need to be messing with the connections (to split for charging).
As I mentioned before, just make sure you google how to use LiPos safely.
There are 4 port chargers that would allow charging all three simultaneously like this one:
https://www.amazon.com/gp/product/B0872 ... 9JDF&psc=1
Hitec makes one too (X4). But these can only charge at a 10A rate, so you may want to shop around.
The 48Ah you said is not right. You'd still only get 16Ah. You'd have 16Ah x 66V = 1056 Wh, which is what matters.
Also, you need to make sure the controller you're using can handle 66V. I think the stock X controller spec is 60V. Don't know how conservative that is, but you should research that too. OR get a better controller that will allow higher voltage AND give you better circuitry (incl. better FETs) for increased efficiency.
Or, of course, you could just swap one of the 22.2V units for a 14.8V so you can safely use the X controller.
If you like Turnigy, they make one:
https://www.amazon.com/Turnigy-High-Cap ... 146&sr=8-2