You probably need to provide more detail on the circumstances it stops charging at 81v.
E.g.
1. Your BMS will kill the charge early if one cell is over limit;
2. As your battery gets older, internal resistance goes up, so as the battery voltage gets close to the charger voltage, the rate of charge slows - if the battery is really unhealthy, possibly so low that the charger cuts off - but might resume if you turn up the charging rate, or disconnect/reconnect.
3. Could be something faulty in either the BMS or the charger.
Care to provide more details on how you know it's stopped at 81v, and what you've tried so far to get solve it?