Offgassing usually refers to normal lifetime (or death-time) behaviour of many products, all manmade afaik.
It was my impression these include plywood, particle board, paints, plastics, carpet, etc etc.
New car smell? Offgas. New house smell? Offgas. Plastics literally offgas their entire lifespan, similar to radioactive material emitting radiation as it decays. If you ever look into granite VS 'quartz'(tm) countertops, you will get to choose from good old irradiation or more 'hip' offgassing
http://www.wisegeek.com/what-is-offgassing.htm
But I find it doubtful that's what you were asking about, re:battery? Sure they all 'offgas' to some degree, but if a battery is 'venting' - that's another story. Likely a story soon to conclude, for the venting cells. If a cell is noticably venting it's usally a fair assumption it's shot, so imo plan on replacing it/them as they will only bring down the rest of the cell string(s) with them. And yes the elecrolyte is some nasty stuff, treat it like you would the acid from a lead battery, imo.