http://www3.interscience.wiley.com/journal/122662143/abstract?CRETRY=1&SRETRY=0
Rapid Research Letter
Si nanowire arrays as anodes in Li ion batteries
H. Föll *, H. Hartz, E. Ossei-Wusu, J. Carstensen, O. Riemenschneider
Institute for Materials Science, Christian-Albrechts-University of Kiel, Kaiserstr. 2, 24143 Kiel, Germany
email: H. Föll (hf@tf.uni-kiel.de)
*Correspondence to H. Föll, Institute for Materials Science, Christian-Albrechts-University of Kiel, Kaiserstr. 2, 24143 Kiel, Germany
Keywords
81.05.Cy • 81.07.-b • 82.45.Vp • 82.47.-a • 82.47.Aa
Abstract
Si nanowires can incorporate large amounts of Li without fracturing and are thus prime candidates for anodes in Li ion batteries. Anodes made from Si nanowires offer a specific capacity per gram more then 10 times larger than the present graphite standard. It is
shown how optimized Si nanowire arrays embedded in Cu can be produced in a relatively simple way employing macropore etching in Si followed by chemical etching and Cu galvanic deposition. First tests of these arrays in half-cells and batteries demonstrated a substantially increased capacity, small irreversible losses and cycle stability. In particular more than 60 charge/discharge cycles could be realized without loss of capacity. (© 2010 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
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Received: 15 October 2009; Revised: 21 October 2009; Accepted: 21 October 2009
Digital Object Identifier (DOI)
10.1002/pssr.200903344 About DOI