YoSamES said:
OK, so I see various LiMn chemistry labels mentioned. From what Dave said, I've learned that Li-Ion is LiMnNiCo, and Cephalotus mentions LiMn2O4.
Are all of today's "Li-Ion" the same chemistry that Dave mentioned, or are there several flavors being sold as Li-Ion?
What chemistry are the batteries marketed specifically as LiMn? For instance, I'm looking at what is sold by
http://www.electricrider.com
The bottom line question: It sounds like any of the LiMn flavors will be good enough for my application. Yes? Or should I be looking at a particular one?
LiMn = LiMn2O4 (or at least should be, sometimes people call other cell chemistries LiMn).
The most popular cells are those from Sony (US18650V...) that have been namend "Konion" by RC enthusiasts. There are some other manufacturers of LiMn2O4 cells like Sanyo/Panasonic UR18650E.
they are not popular here (I don't know why) but very popular in the ebike community in Germany.
Sony Konion cells don#t have ultra high discharge rates (but they are good), they don't have ultra high capacity (but they are quite good) and they don't lastvfoever (but the are quitegood).
Keep them between 3,2V and 4,1V and they should be fine for 500-1000 cycles. Store them cool and below 3,8V and they will last 10 years.
You don't hage to worry about ab BMS, because those are the only cells that simply don't need one. You don't need to worry about self dischrage, because with those cells self discharge simply does not exist. You can store them for 5 years, if you like so.
Just keep them above 3,2V/cells (2,0V or even 1,5V does not kill the cells, but it will lower life expectancy), keep them below 4,1V (you can use 4,2V but that cuts cycle life in half) and this is it.
They only method to kill them is to get them to hot during soldering, so buy packs from someone qho connects them professionally. Add balancing cables to messure cell voltage, if you like to do so from time to time, but it is not needed.
bionX used these cells without a BMS in their batteries, Bosch sold millions of power tools with these cells without a BMS.
And the best thing: They are quite cheap.
LiFePO4 weights 2 times more than LiMn2O4 and costs more and you need a BMS. LiPolys offer high power, but they have to be babied and monitored and you have to become a battery expert if you don't want to have the risk of fire. If the electronic of the BMS fails or a cable disconnects and you don't recognise it you may have a problem... Some last long, others don't.
LiNiCo(Al)Mn chemistries (from consumer electronics) have higher eneregy density, but suck at high power and/or low temperatures and they also need a BMS...
"The best" chemistry does not exist, every chemistry offers advanatges and disadvanatges, so you have to chose what suit your needs or tzhe needs of your wife.
Does she wnat to become an expert in battery managemnet and wants to have ultra high power and accepts the risk of fire -> Buy lipo
If you want you battery to last for 3.000 cycles and you don't mind the weight and the cost -> buy the best LiFePO4 available (don't buy the cheap ones)
If you want super high energy density and you are willing to pay for it and if you don't need high power, buy LiCoNi(Al)Mn cells
If you are happy with moderate power, moderate cycle life time and if you want a reasonable cheap and care free battery -> I would recommend Sony "Konion" LiMn2O4 cells. US18650VTC4 for high power and long lifetime, US18650V3 for less money. Don't solder them yourself, if you don't exactly know, what to do, buy them from someone who does this professionally. This is money very well spent.
My parents use Bosch multitools with "Konion" battery packs that are quite heavily abused in an electric law mower and are now 6-7 years old. Those cells have never seen a BMS or any other "maintenance", they are stored on the shelf during winter and they are still perfectly good.