I think I'm going to answer my own question posted above.
"Never overlook the obvious"
The 'mOhm' in the CA manual stands for Milli Ohm, not Mega Ohm.
Since Volts = Amps x Ohms, and my shunt is 50 mv at 100 amps, I can calculate the ohms, which should be 0.500 milli ohms in High Range mode of...