Some crytalyte controllers have a 72v capability, but I never read of GM 48v ones being able to take more than 48v. The actual upper limit is likely to be the 63v capacitors inside, so 63v fully charged is as high as you can go. Some 48v lifepo4 batteries come off the charger at about 59-60v. If you use RC lipo, 15s is 63v fully charged.
So you'll just have to get a new controller for 72v. Or make it into one.