Yes, you can add more batteries. Try to keep them the same chemistry unless you really know what you're doing, and copy like for like - Most batteries will tell you how many cells in series - E.g. anything from 12 cells to 14 cells in lithium can be vaguely called "48v", but if you get the number wrong, you could cause yourself all sorts of world of hurt, ranging from getting virtually no additional range, to setting the bike on fire.
Best way to extend range? You could write a decent sized paper on that, but here's the basics:
1. Pedal - Which makes the style you were looking at a little poor - Yes they have pedals, but they aren't designed for efficient pedaling, and 176lbs? I hope you have legs like Lance Armstrong and a good supply of steroids to match.
2. Energy consumption increases exponentially to speed, although until about 25mph, this is not a huge contributor. If your new preferred bike goes over 25mph, watch your speed. See graph below, especially the impact of wind:
3. On hills where the bike can't put enough power through to keep up speed, as counter intuitive as it seems, lower the throttle, and pedal. Electric motors are inefficient when they are unable to get to at least 70% of their "desired" speed, so if you can't change the hill, change the "Desired" speed, by lowering the throttle input.
4. If you are using lead acid, look up the Peukert's Effect. The faster you use energy, the less there is to use.
5. You can maybe get very marginal gains by playing around with aerodynamics and road friction. Getting thinner tyres, running them at very high pressures, changing your seating position to sit hunched, etc.
To be honest, almost none of the above is really worth it. My approach would be:
1. Only consider bikes with lithium batteries. Peukert's effect will kill you, and will limit the rate of charge.
2. Get the biggest fastest charger you can fit on your bike. I don't know where you live, but in Australia, all power points must be rated a minimum of 2400w, and in reality can handle a fair bit more than that. If it was me, I'd be getting a 2400w charger, or two 1200w chargers, or three 800w chargers.
Then, as you get to know your regular restaurants (Sorry, don't know what post mates is, but I suspect it's uber eats for mail/documents/couriers?), I'd ask if I can charge while they sort out the pick up. 5 minutes of 2400w is still 200wh. I have no idea how far that will take you on an eScooter, but on an eBike, that's easily 8-10 miles in 5 mins.
If the order is already ready for you all the time, and the above isn't feasible, figure out where the public charging points are - In Australia, they are often on lamp-posts, side of buildings (Don't trespass), in car parks of shopping centres, etc. Just take a guerilla charge between jobs, or if you have to, refuse jobs for 20 minutes to refuel.