Bottom balancing is a strategy that seems to have some smart and passionate followers when using LiFePO4.
Vehicles generally continue to use NCA/NCM lithium-Ion chemistries due to them providing the most power and range in the smallest package.
LiFePO4 is very fire-safe, so I've seen it used on small airplanes to start thr engine, and RV 48V power systems.
If the only BMS failure mode was to kill a cell or pack, it would be less of an issue. However a BMS is also supposed to prevent a cell overcharge, which is a major cause of pack fires.
A bulk charger could charge a 2S pack to 8.4V, with one P-group at 4.0V and the other at 4.4V. Of course if all the cells are of a consistent quality and internal resistance, this wouldn't happen, regardless of the BMS.
Storing a pack at a full 4.2V per cell will erode its capacity.
For pack life and fire safety, charge to 90%. Nothing wrong with charging the pack to a full charge just before a ride, just don't store it fo a week at a full charge..