My understanding is that the chemistry provides the oxygen, the fuel and the ignition temperature in many cases so it may not be necessary for outside oxygen at all.
18650's are already contained in small volume cans, and they have burned.
We've seen Headways burn nicely, they are in cans.
A quick search turns up no Nissan Leaf fires, which is quite a good track record, perhaps their cans do help. They have a rather extensive packaging arrangement for their cells that significantly reduces the chances of mechanical damage to the pouches inside.
It takes a complete system design to safeguard high energy batteries. No one component is sufficient. Preventing mechanical damage, shorts, keeping them in a safe thermal temperature range, preventing overdischarging and overcharging is ALL required for battery safety.