I built a few 2WD bikes and one with three motors. I always found the main problem was traction on the front because the torque from the back motor unloads the front one. That means that you need a way of modulating the power to the front one. Are you having any problems with traction on the front?
Normal throttles are speed control devices, so are not really suitable. You need something that controls the current. I found a good solution was to use a KT control with pedal assist. Each level of the pedal assist is a different power, so on level 1, it's only about 100w, and you can turn the power up when you're at higher speed or use the throttle then. You can use a single pedal sensor to work both throttles if the controllers share the same ground. just splice the signal wire. on the second controller, you don't need a 5v and ground - just the signal wire. It's the same with the throttle.