If you use a high amp-draw hub like a 9C, you have to have at least a 15aH sized battery to keep voltage sag on accelleration down to a minimum. So, if you don't want the size or expense of a 15-20 aH pack of LiFePO4, go for the LiPo.
LiPo will give you very little voltage sag, so your acceleration will be better, but as stated abbove, your top-speed will be 1-2 MPH lower.