Yes, if he already has 16 packs, then buying 12 more would allow him to build a 48v pack of about 17.5 ah size.
If it's not been made clear yet, when you do get a "48v" 14s lico bms, each of your four packs would be one cell to the bms. One wire to the bms per each 4 cell group on the positive terminal. last bms wire on the end negative terminal. If you buy more 4p packs, then you can parallel the packs into 8 cell groups for a total of 17.5 ah on the entire 14s pack.
The spec sheet says discharge at .5c max. That means you would have a pack able to discharge 8.75 amps. (if you make an 8p pack) That's getting better, but if your bike has a 20 amps controller, you'd have to ride awfully careful to avoid discharging it a 15 amps, thus ruining your cells. I would believe I'm going to win the lottery before I believe in 2c burst rate not damaging those cells. But a 1c rate sounds plausible, so a 15 amps controller would work if ridden incredibly carefully.
Buying an even more, you could build a 24 ah pack, that would have a chance of lasting, if you have a typical 22 amps controller on that motor.
So, you gonna have to limit amps. Pop open that controller, and cut one of the two shunt wires, so you have an 11 amps controller. That will give you power to cruise, and prevent you from ruining a 17 ah pack. It will be a pokey bike, but not ruin your 16 ah pack.
If you just make an 8 ah pack, you need to get a tiny scooter. Welcome to ebikes, where batteries cost all you have, no matter how much you have.
