Instead of electrolyzing water, he is pumping a bucketload of energy into it, raising the temperature "to 1500 C" (certainly possible here), producing superheated steam at the surface of the water. The escaping steam carries dissolved ions in it, and at 1500 C (or actually quite a few degrees lower), metal atoms in particular emit visible light: sodium: yellow, potassium and calcium: red, etc. So it's easy to get a yellow-orange "flame" which is not a flame at all. If he really had found a way to electrolyze, then burn salt water, then putting his hand into the microwaves would catch it on fire quickly. After all, what is blood? Salt water with some other junk (cells, proteins, cholesterol) floating in it. (By the way, when hydrogen burns, it produces a very faint bluish flame, not yellow-orange.)