The nominal ratings of each cell can be confusing. S is for series, and when cells are configured in series, the voltage is added, but the Amp-hours (Ah) which is a rough indication of range, is not changed. When you add cells together in parallel, the voltage of the pack stays the same, but the Ah are added together.
LiPo means Lithium Polymer, but there is a lot more information that is not in the name. The "nominal" voltage is the average voltage across the entire useage cycle. If you charge a pack to 4.10V per cell (in series), then a 6S pack would be 6 X 4.10 = 24.6V. If you set the Low Voltage Cutoff (LVC) at 3.3V, then the battery will cut out after running the E-bike for a while, and the 6S voltage is down to 6 X 3.30V = 19.3V
Some builders will charge their pack to 4.15V or 4.20V per cell in order to get a hair more range, but I have been convinced that 4.10V per cell is the best compromise. The LVC can be set lower, maybe 3.0V per cell.
The nominal voltage of LiPo is generally listed at 3.7V per cell, so a 6S pack would be 22.2V, 10S is 37.0V, 12S would be 44.4V, 13S is 48.1V
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The parallel strings determine the amount of amps the pack puts out, and also how much range the pack has. If you make the parallel strings out of 5 cells (5P), and the cell is rated for a peak of 10 amps (10A), then that pack would put out a peak of 50A. If you use a cell that has 3000-mAh (one thousand milli amp hours is equal to one Amp hour), then a pack made from 5P strings of 3000-mAh cells would have 15000-mAh (or 15-Ah).
A pack might be called a 12S / 5P pack. The nominal voltage would be 44.4V, but the peak voltage when fully charged is 12 X 4.10V, so 49.2V