snowranger
10 kW
Overnight usually. This is the first time it has only reached 55 volts. Do cells go out of balance so suddenly?
I don't have enough experience with bulged cells to know how they perform. It could be that they still can charge up to 3.7V, but have less capacity.snowranger said:To my surprise, the pack hit 60.5 volts last night with all cells around 3.7 V. Now I'm wondering if I have a problem at all, and maybe that bulge was there from the beginning.
Bummer. You've definitly had your share to problems. Were your previous damage cells bulged?mingonn said:Another cell bites the dust. Repalced 2 100km ago now another has gone, looks like a neighbour to the one I replaced but will check tonight, I am guessing the swelling of the previous failures damaged the neighbouring cell, will pop the hood tonight and check.
My pack came wrapped in heat shrink which offered little give, if lifepo4 is anything like LiPo there is always some swelling when the cells are first charged. I suspect the pressure due to this initial swelling has caused all my problems. I am not sure if he heat shrinks all the packs now but I am guessing duct tape offers a bit more room for expansion.
Back to Ping for more replacements for now.
Derek
Some (new) cells are swollen - can I still use them?
The manufacturer says swelling is normal if cells are not under compression. However, one should put these cells under compression as soon as possible. They must be compressed in a discharged state, preferably before the very first charging. Usually the cells come preconfigured as a pack of several cells with two end-plates and steel straps that press the plates together which provides sufficient compression. However, sometimes the cells are sold loose. In this case they can swell and the customer should design his own way of compressing them - for example with plates and studs or by mounting them into a strong box.
Can I use the cells without compression?
Solid state Lithium-Ion cells have a very thin solid electrolyte. The electrodes need to be in contact with this solid electrolyte. In case of expansion, the solid electrolyte will not be able to settle down like a liquid electrolyte and therefore the electrodes may lose contact with the electrolyte. This leads to a reduction in capacity. Compression is required in order to prevent this expansion, the ThunderSky cells PP case is not strong enough to provide this compression by itself, so that the pack requires external compression. So the answer is NO - do not use the cells without compression.
That is interesting. The one cell from my pack that did swell happened when I took the pack apart to replace a bad cell group. The swollen cell was the next in line, so it had no compression. It sat like that for over a week while I was waiting for the replacement parts. It was during that time it swelled. Maybe it was the lack of compression that caused it. Makes me wonder if it's worth adding end plates to the pack.torrent99 said:Found an interesting website with regards to bulging cells:
http://www.reapsystems.co.uk/faq7.html
Some (new) cells are swollen - can I still use them?
The manufacturer says swelling is normal if cells are not under compression. However, one should put these cells under compression as soon as possible. They must be compressed in a discharged state, preferably before the very first charging. Usually the cells come preconfigured as a pack of several cells with two end-plates and steel straps that press the plates together which provides sufficient compression. However, sometimes the cells are sold loose. In this case they can swell and the customer should design his own way of compressing them - for example with plates and studs or by mounting them into a strong box.
AND
Can I use the cells without compression?
Solid state Lithium-Ion cells have a very thin solid electrolyte. The electrodes need to be in contact with this solid electrolyte. In case of expansion, the solid electrolyte will not be able to settle down like a liquid electrolyte and therefore the electrodes may lose contact with the electrolyte. This leads to a reduction in capacity. Compression is required in order to prevent this expansion, the ThunderSky cells PP case is not strong enough to provide this compression by itself, so that the pack requires external compression. So the answer is NO - do not use the cells without compression.
Interesting eh?