JackFlorey
100 kW
Enphase sells a system that will isolate your panels from the grid and allow you to island them safely, and then run off the power provided. You'd need their isolation switch and at least one battery.I am thinking of putting a splitter between the panel and the micro inverter for one of the panels to provide a way for me to access some dc power directly from a single panel during a power outage.
If you want to do something with DC power, I'd recommend just getting a few more panels and setting up a completely separate system. Panels are so cheap these days that it's not worth it to mess around with your existing (working) system.