Rosin core lead/tin 60/40 should be the ideal solder for that wire.
Lead/tin solder sticks to silver and copper both extremely well. It should be some of the most simple heavy-gauge wire soldering you've ever done.
If you're not able to solder to it, and you're actually getting the temperature right, then it's not silver-plated copper wire you're dealing with, but rather aluminum wire. In this case, unless you're a pro and have zinc solders and the right flux, I would just swap to a different wire.