Sunstone has some great electrodes, I'm planning on buying a few and testing. They also have few materials to chose from, copper, tungsten, tungsten-copper, and molybdenum.
I use pure copper 10mm2 solid wire, with tips machined to have a smooth cone like shape with half-globe like ending. I'm thinking on getting a custom tool done which would make it easier and faster to get such shape and also improve consistency, because this material works well and sunstone tips would bring up the cost, and I'm not sure if it's necessary.
Also my attachment system allows attaching tips to wire without soldering, so I can use any material if I wanted to, not just pure copper.