Boric Acid + Oil = The slipperiest hardest bearing surface ever. Easily? Experimentation Reqd.

I did find some research comparing MoS2 to BA directly and the results are pretty decent. Here are the two most relevant graphs:
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So basically friction wise it's better only if the particle size is small enough, although I think it's kind of unfair to compare MoS2 only at 5um. It easily beats the 4um BA so how would smaller MoS2 perform, possibly far better. The wear on the other hand is more interesting and the paper does go into caveats about how the particle size starts doing weird stuff at some point and that could be the reason the MoS2 did so much worse than just the oil. Basically if particles are too large they can add to abrasive wear and if too small they can cause adhesive wear depending on the materials and surface. Also these tests were done with copper on aluminum which seems kind of weird to me. Regardless the fact that the 4um BA did so much better than the 5um MoS2 I think says something.

I think the takeaway is smaller is better for BA although not sure about sourcing 20nm BA. And this is still not some magic additive, it's good at some things, better in some ways, worse in others (like it's comparatively terrible temperature stability).

Although thinking about it there are a lot of other variables here, the reason cited in the paper for smaller is better is just because they can fit between the metals better, get sucked in and caught on micro surface features. Which makes me wonder how the lubricant effects things, for instance and grease vs an oil. Also with chain wax the idea is the wax is solid so it stays in place better, basically getting smeared in between the metals surfaces and harder to push out of the way than oil. But is still gets pushed all the way though and the additives start to work so idk.

I still think adding BA to motor oil is probably a bad idea, probably for some of the same reasons they don't add MoS2 to modern motor oils, it doesn't stay suspended well, clogs filters, interferes with other additives, causes particle emissions that coat cats, etc.
 
Ok I actually had the chance to read through the patent from the patent it sounds to work a bit differently than you explained. From the patent it seems the boric acid is acting just like MoS2 or WS2 that is through slipping of the layers in it's lamellar crystalline structure. The only reference to reacting with water is "Boric oxide particles mixed with polymers form boric acid particles on the exposed surface by reacting with moisture in the surrounding atmosphere." So just another way to get the boric acid but only on the surface of a polymer instead of adding it directly. I don't see anything about forming a super hard layer by reacting with the metal.

If this is the case I wonder the differences in performance of BA, MoS2, and WS2. I know WS2 is a fair bit lower friction than MoS2, I used MoS2 in my wax but only because I didn't know about WS2 at the time. Regardless these types of additives have are not magic, they are very effective EP additives and lower friction nicely under EP conditions but they don't lower friction at lower pressure levels. Basically you need enough pressure to squeeze the layers in between the base metal and get the layers to start slipping, at low pressures the particals just sorta move around and can actually increase wear if the base material is too soft. This is why you don't want to use this these additives with polymer gears. Anyway an interesting thing I noticed is that the patent talks about combing it with other additives. I've seen interesting papers that show PTFE additives acturally work very synergisticly with MoS2 because the PTFE lowers the friction at lower pressures where the MoS2 does not and vise versa. For a chain lube through I see no reason why BA wouldn't work well, better than the current benchmark that is WS2 I'm not sure. And there is also the issue of the BA being acidic of course which can be beneficial or harmful depending on conditions I think.

I don't see anything on BA forming any super hard iron boron compouds like in boron treated steel which typically requires very high termperatures.

Edit:
Here is an interesting comparison: Table - PMC

That paper was an interesting read. Thx scianiac. I have been concentrating on BA...

Yes Boric Oxide does form on the metal surfaces.
I'm work on what's turning out to be a freaking thesis, with a hundred open tabs, on the whole story and will post it later if I manage to remain sane! :)

I'll also answer your above concerns.
(NB that any powder in filters will dissolve into the water (of combustion) that gets into engine oil over time... )

For the mean time; here's a paper with some nice pics and plenty of references to follow:
1-s2.0-S0301679X22001141-gr9.jpg

NB that these researchers are confusing and discombobulating themselves by feeding the test surface with boric acid dissolved in ethanol and mixed with oil which largely precludes it's exposure to moisture in the air until well into the surface sliding tests.
The 'atmospheric' conditions are also nothing like those in combustion chambers. IMHO.

They then clean off the oil etc from the sample metal surface before later! looking for the BO layer, exposing any Boric Oxide layer to air moisture and turning the layer they are looking for from metal bonded BO into BA...

But more on all that later.

BA and wax:
The only info I have found so far is this patent.

Water-series wax-base lubricant and its preparing process​

A water-series wax-base lubricant is prepared from synthetic fatty amide wax, organic borate, surfactant and water through emulsifying. Its advantages include uniform adsorption layer, high friction-reducing and antiwear effect, high lubricating, anti-rust, degreasing and cooling nature, and less pollution...

NB I haven't fully read/swatted it yet due to this freaking 'thesis'! :)
 
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