The VoltPhreaks chargers have the CC/CV set a bit higher than what is really needed, which is a minimum of 3.65V. I've got 16 of them and the cutoffs range from about 3.75V up to as high as 3.90. It won't hurt the cells doing this, as far as I can tell.
With LiFePO4 cells, the voltage rises at a slow steady rate, as it charges, until the cell gets to about 3.65-3.70V, which if you stopped there is about about 85% full. Above that point the voltage rises at a much higher rate. It will take only seconds to get to 4.0V, or higher. In order to get the last 15% into the "tank", you need to hold the voltage at somewhere between 3.65-3.70V, and let the current taper off. When it gets down under about 50mA, or so, the cell is about as full as it is going to get. With LiFePO4 cells, the crossover point voltage is not all that critical. I've tested cells using a VP charger that has a crossover set to 3.84V, and then tested the same cells using our BMS, which has a 3.68V crossover point. Once the surface charge is burned off, which with some cells happens on its own, but with others you need to put a very slight load on the cells for a few seconds, to get rid of the surface charge, the cell ends up with the same "full" voltage, and has the same capacity.
-- Gary