The "reserve" battery, if not paralleled with the other one, will have to be able to supply the same kind of power / current that the other one does, by itself. If it can't, several possible problems can happen.
If the BMS isn't capable of the current, it can simply fail. Some failures are silent, just FETs failing shorted and leaving the BMS unable to protect the cells from overcharge or overdischarge, and you wont' even know this has happened or that the cells are being damaged, until more severe symptoms (up to and including a fire) occur. Sometimes the FETs actually blow up, and all power output ceases. Sometimes they get so hot so fast the solder melts, and that can short things out or the FETs can move on the PCB or even fall off.
If the BMS can handle the current but the cells can't, then when it's near full charge it may "work" but under high power demands the voltage may sag enough to notice it doesn't respond like it should. Less than full, the sag may begin to actually cause the controller or the BMS to shutdown to try to protect the pack against overload. The cells will heat up more than they should in either case, and be stressed, and won't have as long a lifespan as normal.
If the outputs of the two packs are always paralleled during a ride, then they will work together to supply power, and performance of the system may even improve (because there will be less voltage sag). They will drain together, and the ride will simply last proportionally longer with the both packs than with just the first one.
To connect them the first time, they have to be at the same voltage. Easiest is to first fully charge both of them, then verify theyr'e the same voltage before connection.
There are a few things to take care of when paralleling packs, it depends on the BMS in each one. If the BMS both have common charge/discharge ports, then it's simple--just connect the two in parallel, and leave them that way all the time, for both charging and discharging.
If either BMS has a separate charge / discharge port, then you should disconnect it from the other pack when doing the "opposite thing". meaning, if you are charging it, disconnect it's discharge port. If discharging it, disconnect it's charge port. That keeps the other battery from backfeeding it in a potentially problematic way.
Alternately, using the battery Y-connectors to prevent any backfeeding would also work, but you will need them on charge and discharge ports if they are separate on your BMSs. .