liveforphysics
100 TW
A battery needs no flaws to explode when a 3s is paralleled to a 4s. Both packs are doing exactly what they are supposed to do in that situation. The 4s pack is discharging lots of current as it's voltage is pulled down a bit, the 3s is charging at some extremely high rate as it's voltage is pulled up. Eventually they are going to exceed the 3s batteries ability to accept more charge, it's going to undergo some decomposition that is exothermic, it's going to ignite the solvents and separator materials in the battery and keep them fed with the off-gassed oxygen from the cobalt oxide thermal decomposition to ensure the flames stay in a strong rushing burn until readily combustible components are devoured and oxidized. This generally makes a "whoosh" sound while it's happening, and just lasts a few seconds, maybe up to 10seconds of intense heat/flames. Then it has a period of minutes where comparatively minor materials like the shrink-wrap and tape and sticker and sticker adhesive etc all burn and make a nasty smokey stinky mess.
We've got this process down pretty well now. In this case, it has nothing to do with getting a high quality or low quality product. It's simply what a high C-rate capable cell is going to do in an extreme overcharge situation (which is what occurs when you connect a 3s to a 4s). As an example, A123 pouches do the same thing in extreme overcharge, as do most all of the cells capable of high C-rates. The cells that can survive something like this without bursting into flames are the ones that have such high internal resistances that they make real high performance from a small battery pack impossible. If you can settle for lower performance or the need to carry a much physically larger heavier battery (because you have to have some many high-resistance cells to discharge the current you require for high performance levels).
I think the big lesson there is one we've seen learned many dozens of times with varying degrees of failure outcomes, check and double-check wiring connections before mating, and ideally key connectors to make it impossible to fumble together connections that result in flames.
We've got this process down pretty well now. In this case, it has nothing to do with getting a high quality or low quality product. It's simply what a high C-rate capable cell is going to do in an extreme overcharge situation (which is what occurs when you connect a 3s to a 4s). As an example, A123 pouches do the same thing in extreme overcharge, as do most all of the cells capable of high C-rates. The cells that can survive something like this without bursting into flames are the ones that have such high internal resistances that they make real high performance from a small battery pack impossible. If you can settle for lower performance or the need to carry a much physically larger heavier battery (because you have to have some many high-resistance cells to discharge the current you require for high performance levels).
I think the big lesson there is one we've seen learned many dozens of times with varying degrees of failure outcomes, check and double-check wiring connections before mating, and ideally key connectors to make it impossible to fumble together connections that result in flames.