"LiPo Fire" statistic comparison.

StudEbiker

100 kW
Joined
Apr 13, 2009
Messages
1,999
Location
Ashland, OR, USA
Having yet another LiPo fire here on the board, I thought it would be interesting if we had kept a history of exactly how many LiPo fires have occurred on this board. Realizing this isn't likely to happen, but still looking for a way to see it as a statistic, I entered in a search of "lipo fire" in the search and got 2388 results, as a comparison, I also entered "lifepo4 fire" and got 611 matches.

Also, (using the Google search) a search of "lipo kff" results in 458 results, "lifepo4 kff" had "160 results."
 
One fire causes a flurry of responses, all notching up the figures in your google search. It would be more useful if you set up a poll on survey monkey or the like and collated the data that way. If you do report a battery fire, then the pics or it didn't happen rule should apply (or something so user member LiPofireno0b69 doesn't spam-bomb the survey with horror stories). You could also get some meaningful analysis of what was likely to have caused the fire. A fire is a fire, but some are more avoidable than others.
 
jonescg said:
One fire causes a flurry of responses, all notching up the figures in your google search. It would be more useful if you set up a poll on survey monkey or the like and collated the data that way. If you do report a battery fire, then the pics or it didn't happen rule should apply (or something so user member LiPofireno0b69 doesn't spam-bomb the survey with horror stories). You could also get some meaningful analysis of what was likely to have caused the fire. A fire is a fire, but some are more avoidable than others.

Yes, but there can be no question that there are far fewer Lifepo4 fires than there are lipo fires. Using your argument that one fire causes a flurry of responses is true. However, I would think that the rarity of any LiFePo4 fire would produce a higher percentage of responses. Also, I can't think of even a single instance of kff from LiFePo4.

It is an unscientific comparison for sure, but I do think there is something to be learned from it.

Yes, some fires are more avoidable than others, and all lipo fires are avoidable by not using lipo.
 
There are so few Kentucky Fried Finger events with LiFePO4 because LiFePO4 is usually supplied in a format which doesn't involve finger interaction. Like a Ping Pack is pre-made. A LiPo pack requires the user to assemble it...

It wouldn't be fair to compare event statistics on a chemistry level, as either chemistry has different formats and modes of assembly. I think a good analogy would be like being provided 89 RON gasoline in a sealed plastic jerry can, and another being provided 98 RON gasoline in a open metal pale. Both risky, it's just the packaging which makes it hazardous.
 
Good concept there StudEbiker, tricky to quantify though. No LiPo fires (that were unintentional :wink: ) to report here.

Just like fire departments reccomend that everyone should change the batt's in their smoke detectors when daylight savings time kicks in/off, maybe 'We Who Are Brave and/or Stupid Enough To Run LiPo' should be pulling our packs apart and checking them on the cell level(?) That is what I did today. All good!

Speed safely, -S
 
This is completely unrepresentative, and wholly reliant on my somewhat flawed memory so should be treated with caution, but over the years I can only recall a large handful of battery explosions or fires that have been reported either on ES or one of the other EV forums I look at from time to time.

Ignoring the deliberate experiments (i.e. LFP setting fire to cells for fun), the ones I can recall are:

1) The Headway pack that caught fire and which we discussed here a few months ago.
2) The RC LiCoO2 pack that just started smoking while the guy was riding, which I think ended up as just a cell or cells venting rather than catching fire.
3) My own NiMH pack that caught fire and exploded whilst being charged overnight.
4) The car LiFePO4 pack that caught fire and burned the car out, again whilst being charged overnight.
5) The exploded lead acid battery pictured here a couple of weeks ago.
6) This latest LiCoO2 pack fire
7) The aircraft hold fire that was reported earlier this year, that is believed to have started from a shipment of laptop cells (most probably LiCoO2 ).
8 ) The stories circulated a year or two ago following the recall of laptops due to one or two Sony LiCoO2 cell battery fires.

We know the probable/possible cause of some of these incidents:

Mechanical damage

The Sony laptop battery recall was apparently due to a flaw in the battery pack, we don't know whether this was with the cells, assembly or any internal BMS, but we do know that Sony said that the flaw was exacerbated if the laptop was "jostled", which suggests a mechanical problem that might cause a short.

The Headway pack fire might similarly have been a result of a mechanical problem causing a short, IIRC.

The aircraft cargo hold fire was probably similar, poor packaging that allowed cells to short.

The LiCoO2 pack that vented while the bike was being ridden was probably also from a mechanical cause, maybe some sort of internal short from mechanical cell damage, as I believe the cells were inside a soft bag.

Charging

My NiMH fire was due to a charging fault.
This latest LiCoO2 fire seems to have occurred during charging.
The car LiFePO4 pack fire occurred during charging, and the owner believes that the charger may have been the cause.
The exploded lead acid was caused during charging by operator error.

What might be useful would be if people posted examples of battery fires they know of in this thread, together with enough evidence to allow us to determine probable cause, so that we can put together some form of reasonable risk assessment and come up with the things most likely to cause a battery pack fire.

My gut feeling is that the two top causes are those above, mechanical damage and charging problems. There may well be other causes too, though, and it would be good to get a feel for these. It would also be good to get a feel for just how much safer one type of cell chemistry, or one manufacturer, is over another in practice. I have a feeling that, because the cell chemistry or manufacturer is probably very low down on the risk factors that cause fires, we may well see that things like charging or good practice when assembling packs massively outweighs the small safety advantage that some cell chemistries might appear to give.
 
I think some lipo fires are going unreported on ES.

I know a few cases.

Lets just say if someone loses there garage (or god forbid house or apartment building) to a lipo fire, they are not necessarily going to tell the insurance company it was their home-made lipo pack that set it off and then talk about the lipo fire here.
 
I did a list in the iwki yesterday (or day before, I forget) of ones found simply wiht "lipo fire". It needs to be updated with any other instance people have of all the other chemistries, too.

I don't remember if I got Lyen's fire in there, or the one with the fire int eh front basket of someone's bike.

I also havea few NiMH and NiCD instnaces in that sectoin of the the wiki, in the very long list of assorted posts talkinga bout paralleling those chemistries for either charge or discharge, including the report of Jeremy's fire.
 
anyway lipo is dangerous to use not in air far away. So my choice is panasonic NCR18650A - even safier than lifepo4
 
I don't understand your first sentence.

Even the cells you name there are just as dangerous (more, actually, since if the vents are blocked or fail the can actually explode with shrapnel, unlike a pouch cell) if the conditions for causing the fire occur (overcharge, overheat, mechanical damage, short, etc), if whatever internal protections the cell mgiht have can't stop it.
 
iperov said:
anyway lipo is dangerous to use not in air far away. So my choice is panasonic NCR18650A - even safier than lifepo4

AFAIK, the Panasonic/Sanyo NCR18650A cells use the same chemistry as HK cells (or any other RC type LiPo cells), LiCoO2, a chemistry that is inherently less safe than LiFePO4. Not sure where you got the idea that these were "even safer than LiFePO4" but I'm afraid it's incorrect. Even Panasonic point out in the literature for these cells the normal precautions that have to be taken when using them, and these precautions are the same as those for using RC type LiPo cells.
 
when I short panasonic, its just heating to 100C without burn with maximum 2C rate.
When I short lifepo4, first burning wires.
 
iperov said:
when I short panasonic, its just heating to 100C without burn with maximum 2C rate.
When I short lifepo4, first burning wires.

OK, yes, I understand now. You're saying that the inherent high internal resistance of the Panasonic cells limits the short circuit current. I guess that is a consideration in the overall safety of a home made battery pack.
 
I have deliberately shorted 18650 laptop LiCo cells many times. The cells are permanently damaged, but no fire and no explosion.

iperov: 2C is the highest discharge rate published by Panasonic. When you short a cell the rate is a lot higher. I have discharged those cells at 4C for 5 continuous minutes. The cells got hot but still functional. I have also discharged them at 10C for 10 seconds. Again hot but no damage. Those were just experiments, not recommended or even suggested discharge rates.

I have also deliberately:
1) Overcharged them using a 0.5A, 5.30V charger. They got hot at about 4.7V and failed permanently at around 4.9V. No fire, no explosion.
2) Overdischarged in series forcing voltage reversal. Again hot and permanently damaged but no fire, no explosion.
 
SamTexas said:
I have deliberately shorted 18650 laptop LiCo cells many times. The cells are permanently damaged, but no fire and no explosion.

iperov: 2C is the highest discharge rate published by Panasonic. When you short a cell the rate is a lot higher. I have discharged those cells at 4C for 5 continuous minutes. The cells got hot but still functional. I have also discharged them at 10C for 10 seconds. Again hot but no damage. Those were just experiments, not recommended or even suggested discharge rates.

I have also deliberately:
1) Overcharged them using a 0.5A, 5.30V charger. They got hot at about 4.7V and failed permanently at around 4.9V. No fire, no explosion.
2) Overdischarged in series forcing voltage reversal. Again hot and permanently damaged but no fire, no explosion.

My understanding is that if you overcharge with a charger capable of delivering more current than in your modest 0.5A test (which is only a charge rate of about 0.16C) then the cells can explode or vent and catch fire. Someone here did a similar test with these cells, that demonstrated the violence of the event, but I can't find it right now.

My conclusion would be that like lots of similar LiCoO2 cells, these can tolerate a degree of abuse without catching fire, but if they are abused beyond that (say by a high current bulk charger that doesn't shut down when a cell reaches termination voltage) then they still present a significant risk.
 
Jeremy Harris said:
My understanding is that if you overcharge with a charger capable of delivering more current than in your modest 0.5A test (which is only a charge rate of about 0.16C) then the cells can explode or vent and catch fire.

Jeremy: The overcharge test I did is many times more severe than what could happen on my setup. 18650 laptop LiCo are supposed to be charge at 0.5C or less. That would be 1.3A for a 2.6Ah cell. Lithium chargers are CC/CV and laptop LiCo cells have a relatively high internal resistance. So when the battery approaches the final 4.20V voltage, the actual charge rate is at most 0.13A.

It was never my intent to create a fire or an explosion just for the sake of it. The tests were only done to see what could happen when a mistake was made in practical daily use.
 
A single cell tested in open air is different to dozens of cells in a pack, all insulated by some sort of casing...
 
SamTexas said:
Jeremy: The overcharge test I did is many times more severe than what could happen on my setup. 18650 laptop LiCo are supposed to be charge at 0.5C or less. That would be 1.3A for a 2.6Ah cell. Lithium chargers are CC/CV and laptop LiCo cells have a relatively high internal resistance. So when the battery approaches the final 4.20V voltage, the actual charge rate is at most 0.13A.

It was never my intent to create a fire or an explosion just for the sake of it. The tests were only done to see what could happen when a mistake was made in practical daily use.

I understand, it's just that I didn't want someone to read your specific test, as it relates to your specific application, and then assume that overcharging these cells would always be safe. As ever, the devil is in the detail, and if someone overcharged a pack of a different configuration to yours, with a different charger, the results may well be rather more spectacular. The main safety feature here is the low C rate of these cells, both on charge and discharge, and the correspondingly low maximum charge rate. The downside is that same low C rate gives high cell losses due to I²R, so giving a bit of a hit on performance when compared with cells with lower losses. As ever, there is a trade here between all the various cell parameters, so people will have to weigh up whether or not some of the undoubted benefits of these cells are worth the downsides for their particular application. FWIW, I've been seriously thinking about building a pack with some of these cells, as their high energy density makes them attractive for a low power assist type ebike.
 
Jeremy Harris said:
I understand, it's just that I didn't want someone to read your specific test, as it relates to your specific application, and then assume that overcharging these cells would always be safe.
I did a poor job describing. Let me try again: The test was not specific to my application. It's specific to any and all 18650 laptop LiCo setups. A proper charger for a 10Ah battery should be 5A or less. 10A or less for a 20Ah battery, etc...

The downside is that same low C rate gives high cell losses due to I²R,
The loss is already accounted for. A 2.6Ah (9.62Wh) cell will actually deliver at least 9.62Wh at 0.5C discharge.

FWIW, I've been seriously thinking about building a pack with some of these cells, as their high energy density makes them attractive for a low power assist type ebike.
You'll love it. Using the latest 3.4Ah cells, you can build a 10s4p pack. 4.0lbs, 503Wh. Perfect for a 250W European ebike.
 
SamTexas said:
I did a poor job describing. Let me try again: The test was not specific to my application. It's specific to any and all 18650 laptop LiCo setups. A proper charger for a 10Ah battery should be 5A or less. 10A or less for a 20Ah battery, etc...

I understand where you're coming from, but a very quick and dirty FMECA shows that there are one or two possible, even probable, failure modes in a multi-cell pack that renders your assumption a little unsound. For example, say you have a pack made up from 3P cell groups (so 10.2 Ah) that is 12S overall, with a full charge termination voltage of 50.4 V. You can charge this pack at around 5A maximum (0.5C). Let's take a relatively common failure mode. When a LiCoO2 cell fails it usually either goes open circuit or to a very high internal resistance. The same effect as below would occur if a cell interconnection were to mechanically fail, another failure mode that's been recorded here on ES with cylindrical cell packs.

Let's say only one cell in one of the parallel groups goes open circuit, or the connection breaks between it and it's fellows. You now have a pack with eleven groups being 3P and one group being 2P (this probably wouldn't show on a random cell voltage test, BTW). You charge the pack at 5A as normal, so the 2P group is being overcharged from the start and may warm up a bit. The cells in that group will reach full charge in around 2/3rds of the time that the other cell groups will. At this point in the charge cycle most groups will be at around 3.9V to 4V and the fully charged 2P group will be at 4.2V. The charger will sense a pack voltage of 48.2V (4 x 11 + 4.2 x 1). This is below the CC/CV switching threshold, so the charger will stay in full current mode. The 2P cell group is now being overcharged at 5A, 2.5A per cell, some 5 times greater than in your test. This cell group can hit over 6V before the charger senses the voltage increase and switches from CC to CV, which is probably enough to cause the cells in the 2P group to fail rather more spectacularly than they did during your 0.5 A cell test.

SamTexas said:
The loss is already accounted for. A 2.6Ah (9.62Wh) cell will actually deliver at least 9.62Wh at 0.5C discharge.

I understand what your saying, but the power loss during discharge is still higher than for a similar capacity pack made from lower IR cells.

For example, looking at the NCR18650A data sheet, the IR at 1C seems to be around 0.085 ohms (based on the Panasonic data showing about a 0.2V Vdiff for a 2.36A Idiff). Using the same example as above, a 10.2 Ah, 44V pack (3P, 12S) would have a total IR of about 0.34 ohms. If you were to draw, say, 10A from this pack then the power loss (as wasted heat produced inside the battery pack) would be 34 W.

Looking at some test results for cheap prismatic LiCoO2 cells, the low C rate (15C to 20C) Turnigy packs, it seems that the IR for a 5Ah cell is about 0.0015 ohms per cell, or around 0.009 ohms for a 2P, 12S 10Ah pack. The power wasted as heat inside this pack at 10A discharge would be 0.9W.

The difference is large and real, no matter what current that is pulled from these two packs, the one with the lower IR will always be more efficient and deliver more useful capacity at any given load.
 
Agreed on your single cell, open circuit failure scenario. So what to do? Let say I repeat my test at 2.5A and it passes sucessfully (no fire or explosion). Then you could come back with dual single cell open circuit failure scenario. Where does it end? And what's the solution? Give up battery altogether?

Completely disagree with your second point about loss. Why do I care about the loss that is happening inside the cell? I pay for xyz Wh at 0.5C. I get xyz Wh at 0.5C. Why am I complaining? If anything, I should be thankful because I would get more than xyz Wh if I discharge at a lower rate.
 
SamTexas said:
Agreed on your single cell, open circuit failure scenario. So what to do? Let say I repeat my test at 2.5A and it passes sucessfully (no fire or explosion). Then you could come back with dual single cell open circuit failure scenario. Where does it end? And what's the solution? Give up battery altogether?

Completely disagree with your second point about loss. Why do I care about the loss that is happening inside the cell? I pay for xyz Wh at 0.5C. I get xyz Wh at 0.5C. Why am I complaining?

Use a Hyperion with balance wires connected to charge the pack. It will know what to do.

Watch it on the computer screen and you will see right away what is going on with the pack.

Jeremy is talking about bulk charging ?
 
SamTexas said:
Agreed on your single cell, open circuit failure scenario. So what to do? Let say I repeat my test at 2.5A and it passes sucessfully (no fire or explosion). Then you could come back with dual single cell open circuit failure scenario. Where does it end? And what's the solution? Give up battery altogether?

The simple answer is that there will never be a foolproof way to remove all the risk, all we can do it try and understand where the real risks are and mitigate them as best we can. For example, if the risk of a cell going open circuit, or a cell interconnection failing, can be reduced to such a low level as to fall below whatever we decide is the degree of risk we are prepared to accept, then that's all we need to do. I strongly suspect that laptop cells are being deliberately engineered now to have a high internal resistance, as part of the manufacturers safety strategy, for just this reason. With the decreasing power demand from modern laptops, the cells can get away with having higher losses, particularly if that significantly reduces the risk of fire or explosion from a damage induced short or over-charge event.

Our problem is that, unlike the primary use of these cells in laptops and the like, we want to connect cells in parallel to get the capacity we need. That creates a potential charge failure mode that wasn't anticipated by the cell manufacturer (it also introduces other potential failure modes, too). All we can do is mitigate these as best we can. I strongly suspect that ensuring the cells are mounted securely, with proper regard for possible shock and vibration induced damage, coupled with good cell level control of charging, probably makes a pack made from these cells as safe as any other. Having seen a video of an 18650 exploding from massive over-charge, I don't think we can ever claim that they are safe, but there is every reason to suggest that, for some limited power requirements, they are a pretty reasonable choice as far as safety goes.

SamTexas said:
Completely disagree with your second point about loss. Why do I care about the loss that is happening inside the cell? I pay for xyz Wh at 0.5C. I get xyz Wh at 0.5C. Why am I complaining?

The loss during discharge is important for several reasons:

First of all, 34W of waste heat inside the battery pack from a 1C discharge is a fair bit, it will heat the inside of the pack up, which may or may not be a risk.

Secondly, the effective battery capacity you get is being reduced by that loss. If you have two 10Ah, 44V (440 Wh) nominal battery packs, one with 0.34 ohms IR and one with 0.009 ohms IR, and you use these packs to run two identical ebikes at around 220W (say a constant 5A discharge), then the higher IR pack will waste around 17 Wh as heat in the battery and the lower IR pack will only waste 0.45 Wh as heat in the battery. For a typical ebike that uses around 15 to 16 Wh per mile you will get around an extra mile of range from the lower IR battery pack for the same nominal pack capacity, just because of reduced losses.

Finally there is an efficiency point. Say you charge these two packs at 0.5C (5A). If we assume that both battery packs have a unity Peukert number, then the charging losses for full charge in the higher IR pack will be around 17 Wh, meaning you need to put in 440 + 17 = 457 Wh and the charging losses in the lower IR pack will be around 0.45 Wh, meaning you only need to put in 440 + 0.45 = 440.45 Wh. The higher IR pack is clearly less efficient, in that it needs more energy to charge and gives less energy during discharge.
 
Jeremy Harris said:
The simple answer is that there will never be a foolproof way to remove all the risk, all we can do it try and understand where the real risks are and mitigate them as best we can.
Agreed. Just so other people know: You and I have been discussing the risk involved while bulk charging laptop LiCo cells which is an IMproper way. Charging should be done at a cell level or with a charger capable of monitoring each cell or cell group. In which case, the single, open circuit is no longer an issue.

The loss during discharge is important for several reasons:

First of all, 34W of waste heat inside the battery pack from a 1C discharge is a fair bit, it will heat the inside of the pack up, which may or may not be a risk.
Still disagreeing with you. These cells are designed for 0.5C continuous discharge. And that how they should be used.

Secondly, the effective battery capacity you get is being reduced by that loss. If you have two 10Ah, 44V (440 Wh) nominal battery packs, one with 0.34 ohms IR and one with 0.009 ohms IR, and you use these packs to run two identical ebikes at around 220W (say a constant 5A discharge), then the higher IR pack will waste around 17 Wh as heat in the battery and the lower IR pack will only waste 0.45 Wh as heat in the battery. For a typical ebike that uses around 15 to 16 Wh per mile you will get around an extra mile of range from the lower IR battery pack for the same nominal pack capacity, just because of reduced losses.

Finally there is an efficiency point. Say you charge these two packs at 0.5C (5A). If we assume that both battery packs have a unity Peukert number, then the charging losses for full charge in the higher IR pack will be around 17 Wh, meaning you need to put in 440 + 17 = 457 Wh and the charging losses in the lower IR pack will be around 0.45 Wh, meaning you only need to put in 440 + 0.45 = 440.45 Wh. The higher IR pack is clearly less efficient, in that it needs more energy to charge and gives less energy during discharge.
Everything you said here applies to all lithium cells. So it's a moot point. When a cell is sold by a reputable manufacturer, the consumer is told what to expect via the datasheet. The consumer makes the conscious decision to buy based on the specs provided.
 
Back
Top