Sure, easier without a bms actually. One of the beauties of lipo packs is the way you can quickly, easily, and conveniently change both the size in capacity or the voltage of it. It's just depends on how you plug them together whether you have 36v or 48v.
IMO, the best way to wire it would be 2p first, then start series connecting to the voltage of your choice. But you could also do 1p 15s, if you wanted to use the lighter 1p- 5 ah pack at times for shorter rides.
What you will have to do, is get fixed in your mind what voltage is your new stopping point if you are only looking at pack voltage. If your stopping point was 36v when you ran 10s, It would be 54v at 15s. Both stopping with about 3.6v per cell.
What you can't do, is discharge your 10s till it's empty, then add the 5s boost pack and keep riding. This is obvious if you think it through, but if you just look at "stop at 36v" you could fool yourself that you could keep going after adding 18 more volts.
So if you were using the boost pack for less than the entire ride, you'd still need too stop when the 10s part of it was empty.