See that's more useful, the LR big block has a KV of 62 if I recall so does that mean you are planning on using a 48V battery? Either way top speed at 80% of unloaded speed (KV times voltage) is a very rough area to start IF you are using a controller without MTPA or Field Weakening. LR motors are highly salient IPM motors so respond very well to these, even if you don't drive it beyond the unloaded speed with MTPA (which is a safer idea) it will still have lots of torque at that unloaded speed where a motor driven just with FOC will have zero torque at that speed. So you could use like 100% for that multiplier for instance.
In actuality I wouldn't worry too much, assuming you have a controller that can dish out the amps and a decent battery voltage to work with the range of gearing is pretty wide for a big block, that is lack of starting torque or lack of speed is generally not an issue. It's more often more torque than you can actually use and more speed than it feels safe to go.
For instance I have my Small Block geared incredibly low, 27.4:1 to a 26in wheel, geared for 5-10mph crawling and it will still do 45mph on pavement with draggy DH tires at low pressures. Now that is dumping full phase amps into MTPA so that could cause issues overheating if done for long periods of time in addition to a possibility to instantly nuke the controller but you see my point, I tried to gear it for a top speed of 20mph and it blows past that without trying while having more torque than can really be used with the smaller motor. Of course vehicle and rider weight are a factor as well.
So get the gearing approximately correct, focus on a good controller and battery and then after you ride it you can always tweak the gearing later.
And as for the electronics if you aren't good with them I would just get the high voltage EV ASI kit, pretty much plug and play with the LR motors, all you really have to do is the battery which there are a good number of suppliers of high power batteries out there now. If you do want to do lots of learning then a quality VESC would be my pick, just don't get a cheap shitty one.