Drunkskunk said:
Nicad has a service life rivaling LiFePO4, But with some drawbacks like the memory effect.
stop saying that (& I don't mean just you)
While it's technically true that NiCd exhibits memory under a very specific set of tightly controlled circumstances, it is such a miniscule effect in modern NiCd cells that for all intents & purposes it is a non-existent effect to anyone that doesn't work for NASA, plus the effect is recoverable.
It certainly doesn't warrant all the continued press it keeps getting.
If the intent of this forum is to lead the way in disseminating quality info touching upon all things EV then I plead that ES be the place that this urban legend has a stake driven thru it's heart & finally be laid to rest that it don't continue into this new millennium.
Memory has become the scapegoat for any & every kind of failure mode imaginable in a NiCd cell.
In fact the single most common failure mode (of any chemistry) is that of cell reversal of the 'runt' cell in a pack which has gone out of balance (capacity reduction) brought on by exceeding depth of discharge (80% on nickel).
i.e. letting the fun times roll until you've wrung the last electron from the pack until she don't roll no more b4 recharging is the worst possible thing you can do.
Then when the pack dies a premature deth, the prognosis is to write it off as the result of memory.
The other biggie in small consumer cells particularly that gets the automatic memory label is separator puncture from dentrite growth which is specific to NiCd that forms when sitting on trickle charge for an extended period of time, anything over a month without a discharge.
The puncture results in even higher than normal self discharge so that the cell is down to zero volts within a couple of days.
It's typically flat when you go to use it, then you say "but I just charged it & only used it once!!", you can always count of someone to perk up, "yep, dat dere's de memory", cuz to the end user it appears like a reduction in capacity so it's hard to convince someone it's not memory.
A good NiCd or NiMH should *never* read zero volts, even after it's been sitting discharged for months.
It may not have any discharge capacity left to power a load but there should always be enuf to get a voltmeter reading around one volt open circuit even a year later if the cell is healthy.
You can still get some useful life out of a cell with a separator failure but you have to drain it straight away off the charger.
Dentrite formation is so common cuz NiCds do self discharge rather quickly even normallly so it's tempting to leave the battery on charge continuously so that they're ready to go at all times, but it's best to remove them from the charger after 24 hours & top them up just b4 you need them which is difficult to plan for a lot of times.
There are other failure modes as well but in my experience these two are the most common by far probably responsible for 99% (WAG) of the ded NiCds out there & are not reversible, therefore they are not memory, yet they don't get anywhere near the mention to the extent that memory does that I have seen to educate people of what's really going on here.
You have to charge a battery like you were voting, early & often & nickel batts like to be exercised with an occasional deep discharge (not more than 80% tho) to keep them limber & I've gotten 10 years out of AA NiCd by observing these precautions acting as a human BMS.
So can we part company with the memory boogeyman pls?
Thank you for your cooperation.