Sure it can be done. I'd cut/grind down the 3 spokes first to just the right size so the hub center is centered on the rim. Be sure he understands that you don't want to heat up the magnets during welding, so he us sure to properly sink the heat away instead of traveling up the spokes, since AL has over 5 times the coefficient of thermal conductivity of steel and heat will travel quite rapidly up that spoke.
Welding a flange for spokes right at the hub would have be tricky to avoid heating up those epoxied magnets too much.
BTW, we should have gotten together ahead of time, and made it a 4 wheeler. I have the identical pair of 20" wheels w/ a motor. What's the maximum voltage you've run yours at? The smaller wheel isn't going to slow it down nearly as much as going down to 24V would have.