MitchJi
10 MW
Hi,
How suitable would these batteries be for an EV or Plug-in Hybrid?
http://cleantechnica.com/2013/10/26/new-life-green-weenie-electric-locomotive/
http://www.axionpower.com/PbC_Battery_Overview
How suitable would these batteries be for an EV or Plug-in Hybrid?
http://cleantechnica.com/2013/10/26/new-life-green-weenie-electric-locomotive/
Railway giant Norfolk Southern launched its ambitious all-electric NS 999 locomotive project in 2007, and since then it has been chugging steadily, if slowly, along. The pace has been picking up of late, though. At a recent trade conference, the company and its partner, Axion Power, documented improvements in the locomotive’s battery management system that leapfrogs the technology into the next generation.
Our sister site, Gas2.org, first began covering the NS 999 prototype when it rolled onto the tracks in 2009. Dubbed the “green weenie” by rail fans, the all-electric locomotive sported 1,080 12-volt lead-acid batteries.
There have been some promising tweaks to lead-acid batteries, but the difference occurred earlier this year, when NS 999 switched over to a new lead-carbon battery developed by Axion Power.
The positive electrode follows standard procedure for a conventional lead-acid battery, being composed of lead dioxide. The negative electrode, however, subs in a supercapacitor made of activated carbon for the sponge lead found in a conventional battery, hence the moniker PbC® battery.
Axion explains how the high surface area of its specially formulated activated carbon gets the job done:
At the 7th Annual ASME (American Society of Mechanical Engineers) Rail Transportation Conference in Pennsylvania earlier this month, Axion and Norfolk Southern provided an update on NS 999, comparing the new battery system to the earlier valve-regulated lead-acid battery system.In conventional lead acid batteries the concentration of acid changes from being very concentrated in the charged state to somewhat dilute in the discharged state as the acid is converted to water. In contrast, the PbC® battery stores H+ in the negative electrode in the fully charges state which move to the positive electrode during discharge where they are neutralized to form water. The result is reduced acid concentration swings from the charged to discharged state which reduces grid corrosion on the positive electrode and leads to longer life of the positive electrode.
The report didn’t pull any punches, critiquing the previous iteration of NS 999 for its unwieldy battery management and battery packaging systems, which piled on maintenance costs.
The new PbC® batteries were tested on the Norfolk Southern Hybrid Locomotive Simulator, and the results look promising. According to the report:
PbC® batteries have a unique charging curve, known as “concave down, increasing,” which allows the batteries to self-equalize in strings. This characteristic of PbC® batteries provides for simpler battery management and reduced maintenance charging, while increasing the usable energy available to the string.
We Built This Zero Emission Locomotive!
Before Axion came on board, in its initial stages NS 999 was developed in partnership with Penn State University with an assist from Department of Energy funding (Norfolk Southern has also received $105 million in Recovery Act funding to improve the critical Crescent Corridor freight network, btw).
The Department of Energy also awarded Axion $150,000 last year, to help the company kickstart a commercialization plan for the PbC® battery.

http://www.axionpower.com/PbC_Battery_Overview
http://www.asmeconferences.org/RTDF2013/ViewAcceptedAbstracts.cfmPbC® Battery Overview
Technology and Performance & Economics
Conventional lead acid batteries are comprised of two electrodes: a positive electrode made of lead dioxide (PbO2) and a negative electrode made of sponge lead (Pb). Both the lead dioxide and sponge lead materials are pasted onto lead grids that act as the current collector. Two half reactions occur on the electrodes during charge and discharge that are described by the well known double sulphate theory for lead acid batteries...
The PbC® battery is a hybrid device that uses the standard lead acid battery positive electrode and a supercapacitor negative electrode that is made of activated carbon. The specific type of activated carbon we use has an extremely high surface area (1500 m2/g) and has been specifically formulated by Axion for use in electrochemical applications. During charge and discharge, the positive electrode undergoes the same chemical reaction that occurs in a conventional lead acid battery, i.e. lead dioxide reacts with acid and sulphate ions to form lead sulphate and water. The main difference in the PbC® battery is the replacement of the lead negative electrode with an activated carbon electrode that does not undergo a chemical reaction at all. Instead, the very high surface area activated carbon electrode stores the protons (H+) from the acid in a layer on the surface of the electrode. This new negative half reaction can be written as the following:
Negative Electrode in the PbC® battery technology
nC6x-(H+)x D nC6(x-2)-.(H+)x-2 + 2H+ + 2e- (discharged)
In conventional lead acid batteries the concentration of acid changes from being very concentrated in the charged state to somewhat dilute in the discharged state as the acid is converted to water. In contrast, the PbC® battery stores H+ in the negative electrode in the fully charges state which move to the positive electrode during discharge where they are neutralized to form water. The result is reduced acid concentration swings from the charged to discharged state which reduces grid corrosion on the positive electrode and leads to longer life of the positive electrode.
"Norfolk Southern Railway Company (NS) is developing an all-electric switching locomotive, the NS 999, to provide a zero point source emission electric locomotive option for switching service. The original NS 999 suffered from poor battery management and challenging battery packaging, making maintenance difficult. The rebuilt NS 999, anticipated in the 3rd quarter 2013, will be powered by Axion Power’s PbC® batteries. The Axion PbC® batteries provide increased charge / discharge cycle life and charge acceptance compared to conventional Valve Regulated Lead Acid (VRLA) batteries, as well as increased usable energy when configured in series as ‘long strings.’ NS and Axion will review the challenges of the initial battery management system, improvements to the battery management system, and test results from the Norfolk Southern Hybrid Locomotive Simulator using Axion’s PbC® lead-carbon hybrid battery / supercapacitor. Axion will present test data showing the low variation in strings of PbC® batteries compared to VRLA while simulating locomotive switching. PbC® batteries have a unique charging curve, known as “concave down, increasing,” which allows the batteries to self-equalize in strings. This characteristic of PbC® batteries provides for simpler battery management and reduced maintenance charging, while increasing the usable energy available to the string. "