Based on charging experiments I ran this afternoon I’m going to recant some of what I said earlier

. In a nutshell it’s NOT faster to balance a LiFePO4 pack by the method I describe in earlier posts. The method I described is best used if a shallow discharge of the pack follows the balancing.
For everyday charging and balancing when the differences in cell voltages is not great (<0.20V) leaving a charger connected to the pack until the current flow reaches near zero (not simply when the charger turns green) will yield better results. This is however only true IF:
1)The charger’s output voltage is sufficiently high
2)The charger output remains active and high even when it indicates a green “charge completed†condition. A charger which completely turns off or switches to a lower level will not work as well.
3)The pack is not grossly out of balance.
If the pack is grossly out of balance then it should be manually balanced by bringing the cells up to the same point with a single-cell charger. This can be combined with discharge of high cells if necessary (a 10 ohm resistor rated 5W or better works well enough for smaller packs).
My recommendation then while you're waiting for your single-cell charger is to see if your BMS is working properly when charging and balancing. The best way to do this is to monitor voltage and current while charging (a wattmeter is an invaluable tool for this purpose as it does both simultaneously). Also record the individual cell voltages before charging, directly after charging and 30 minutes after the charger is removed.
Since you said you had two chargers use the one that is outputting the highest voltage (59V+ preferrable) AND be sure its output remains high even when the charge completed LED turns green. If you only have a DVM to work with then monitor the battery voltage connection
on the BMS during a charge cycle. Be sure if it starts at say 54V that it increases over time to the output level of the charger. After the charger turns green make sure the battery voltage remains high (59V+). If during charging the battery voltage stalls and starts dropping sooner than expected, accompanied by the charger LED abruptly going green, then that's an indication the BMS is cutting off the charger (probably due to a cell going to 3.90V+). To verify this you can switch your meter to read AMPS (move leads to current position...and remember to move them back later!) and place it in-line with the charger and battery.
Warning:If you don't know how to measure current then don't because you can blow things up if you get it wrong. If the battery voltage slowly approaches the open circuit voltage of the charger then the LED turns green and the voltage remains high then leave it connected for another hour or two. Again a wattmeter is great here because you can see the current
slowly decrease towards zero as the voltage slowly rises. Once the charger current approaches zero then disconnect the charger and let the BMS do the final balancing but don't expect #16 to be up with the rest. If all is working properly the other 15 cell groups should balance however.
The alternative is to wait for the single-cell charger and use it to charge
each cell to the same point so you know you're golden. Once that's done you'll want to watch cell #16 closely to be sure it can hold the charge. You'll also want to check the other cell voltages after a normal discharge/charge/balancing to be sure they are in fact staying close to one another.
-R