Some thoughts:
If the packs have a BMS, be very sure their parts are rated for the absolute max voltage the system could ever see, because if any BMS shuts down for any reason it will have that entire voltage across it's FETs.
If they can't handle that they'll fail, and that often means failing shorted, which means the BMS is now permanently stuck on, and cannot protect the cells against anything...and since it was already triggered it means the cells are being damaged right then and there, and will only get more damaged as time goes on becuase you won't know the BMS has failed unless you test for it regularly.
0Regarding total system voltage:
--The higher you go in voltage, the more expensive controllers to handle it become.
--higher voltages mean more potential safety considerations in the electrical system; making sure all switches, fuses, etc are rated for that
Regarding capacity: As long as your total wh is the same, then capaciyt is the same. So if you have 3x 30v packs of some capacity (say, 10Ah for simplicity of math), then youc an have a 30v 30Ah pack (3 in parallel), a 60v 10Ah pack (2 in seires, can't use the third), or 90v 10Ah (3 in series). Only the first and last have the same total capacity, the 60v has only 2/3 of the total because of the pack taht can't be used.
So it depends on what packs you actually have and how many for what total capacites you can get.
Regarding range and performance: It takes a lot more power to go faster above around 20mph for unaero-optimized bikes/trikes; if you know the CdA / etc of your fairing you can punch in numbers into various online simulators and calculators such as those at ebikes.ca to find out how much power it will probably take for various speeds under whatever riding conditions you have.
Because it takes more power to go faster, the faster you go the lower your range will be.
Regasrding voltage vs performance: I'd recommend playing iwth the ebikes.ca motor simulator to show yourself how various system configurations with different voltages behave, power / torque / heating / etc curves on your specific riding conditions, whcih will also help you decide what system voltage to use.
I'll leave ride safety stuff up to you; if you're planning on those speeds at all, I'm sure you'll research the necessary things if you haven't already.
