Beagle123 said:
Hi b123.
I think there is another option:
D) Disconnecting all the batteries and charging with one big charger at 4.1v.
Agreed. I missed that one.
The only element missing from this design is a component that instantly switches the batteries from being in series to being in parallel. I beleive this is an invention that would solve everything. I'm envisioning a big switch that contacts all negative to positives when thrown, and disconnects everything when thrown in other direction. I wonder if that exists?
Just a big bunch o' switches that seems unnecessary to me. You seem to be operating under a mistaken impression that chargers in series are not isolated without extra precautions. Two prong chargers like ours' are are always isolated. Hence, no shorts. Hence, no need for a complicated series/parallel switching scheme. And it's not like you didn't already purchase a butt load of single cell chargers anyways.
Small cells are a big problem. The current small format cells cause huge headaches because we have to string so many cells together. Current balancers only handle 8 cells or so, and they must be linked for more cells. Our problems go up exponentially with the number of cells.
No big problem for me, and with 300 on board, I'm the reigning small-cell ebiker 'round here.

It was just a lot more upfront work is all.
More cells = more electronics = more potential for failure = more danger
Agreed. But in the case of small cells, also a lot more redundancy.
Imagine if we tried to power a car. At some point we're going to want something that's 6hp or so.
Tesla motors employs 6,831 of the same laptop cells I use.
I agree though that having the option to use larger cells is definitely better.
The dreamer in me hoped that the car companies would slip-up and use a safe LiFePO4 batteris as a car starter battery. That would be awesome. Imagine if we could go to AutoZone and buy 5 12v batteries.
It'll happen in not too long. 12v lithium batteries are now entering the market as a replacement for motorcycle lead-acid starting batteries.
If we can get any company to consolidate cells into safe, balanced packs, our lives improve exponentially.
It'll take a lot more than batteries to improve my life exponentially. However, if I could replace my need to eat with a 105-year replaceable battery pack, that could be exponentially freeing -- you think?
Reality is overrated anyway -- at least this present reality is.
As far as charging, I think you had a stroke of genius by bypassing all the compllicated electronics and charging at the cell level.
There was no genius stroke involved. Others had shown how they had done the same with SLA and SLA chargers, NiMH and NiMH chargers.
I'd only offer one improvement: I think using a big power-supply might be more reliable and faster.
Agreed. But I'd note that lithium charging time is not inversely proportional to charging current. Charging at 2X current takes more than half as long as 1X current.
I just thought of another possibility: Why are you able to charge with individual chargers without a short? It seems to me that your chargers must be isolating themselves from each other using diodes or something.
Chrimany man (how is cry-man-e spelled ? oh well...) as I've tried quite unsuccessfully to explain, they are already isolated from each other by the very nature of the circuit. You should stop and think about it. There's no added danger of short circuit involved.
I've been studying electronics a bit lately.
Good. Study the part on short circuits and common electrical points again.
That's true of li-cobalt, but not for li-mn. Look at this chart:
http://endless-sphere.com/forums/viewtopic.php?t=2252
So it doesn't blow up, that's very good. Do you happen to know the voltage at which LiMn cells are at immediate and substantial risk of permanent death or irreversible damage?
Would you be able to sleep at night? I would.
Again, it'll take a lot more than that for me to sleep soundly.
Also, I beleive I read in battery university that charging to 4.2 volts is not optimum, and that charging to 4.1v will lengthen battery life.
from battery university:
3.92V/cell is the best upper voltage threshold for cobalt-based lithium-ion. Charging batteries to this voltage level has been shown to double cycle life. Lithium-ion systems for defense applications make use of the lower voltage threshold. The negative is reduced capacity.
Charging only to 4.10V reduced the capacity by 10% but provides a longer service life. Newer cell are capable of delivering a good cycle count with a charge to 4.20 volts per cell.
I mostly agree. After reading the Tesla motor's blog, other materials, and integrating my previous experience accidentally killing some of my cells, I'm of the opinion that LiCo, and probably LiMn, have a "happy range" between 3.80 and 4.0 volts, and that operation outside this range progressively and slowly damages the battery faster than operation within this range.
If you could buy a battery pack that's 10% heavier, but lasts twice as long, wouldn't you want it? I think its a no-brainer.
Unless for some reason (like the weight limit on a bike rack) that 10% made a disproportionate difference on the total systems performance or viability, then yes, that trade-off is also a no-brainer to me. Except I just used my brain to decide that. So maybe not. Arrrggghhh! Do you have to always do that to me!?
Summary:
My current opinion is that the best solution is to charge cells individually with a huge 4.1v (100 amp) charger. Hopefully, someone will make a 12v "Black box" battery soon, then we can charge with a 12v 100 amp charger. I'll look forward to when people ask me, "how long does it take to charge?" (been there?).
My response continues to be that your series/parallel switching scheme is unnecessary added complexity because our chargers are already isolated, and as my experience has proven, happily charge each subpack individually whilst they remain firmly wired in series.
I estimate that my clothes dryer uses about 7200 watts. If it was a battery charger, it could produce 600 amps at 12v. If you had a bike with a battery pack that was 90v, 30ah (drool), my dryer/charger could charge it in 15 minutes. Its time to start converting laundromats into charging stations.
Don't forget that charging faster shortens longevity just like discharging at a higher rate does. Why? Either way the cell heats up more, greatly speeding fatal chemical oxidation degradation. A 10 degree rise in temperature generally doubles the speed of a chemical reaction. I remembered that from General Chemistry -- impressive, eh? But I forgot if that was 10F or 10C.

Probably 10C since metric is the standard in the university science education realm.
As for the laundromat, perhaps they should also work on harnessing the power of static cling.